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is a membrane–bound enzyme that preferentially catalyzes the –methylation of aliphatic sulfhydryl compounds such as captopril and D–penicillamine, whereas is a cytoplasmic enzyme that preferentially catalyzes the –methylation of aromatic and heterocyclic sulfhydryl compounds including anticancer and immunosuppressive thiopurines such as 6–mercaptopurine, 6–thioguanine, and azathioprine