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Melatonin induces reactive oxygen species generation and changes in glutathione levels and reduces viability in human pancreatic stellate cells | Journal of Physiology and Biochemistry | Springer Nature Link

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The catalytic action of His 451 is essential, as demonstrated by mutagenesis studies in which its substitution with a glutamine residue causes the enzyme to retain ≈ 0.4% of the wild-type catalytic activity